Chemical Formula : Al2O₃ , 2SiO₂, 2H₂O

Physical Properties :

Chemical Composition :

Industrial Applications :
China Clay is the heart of several industries like potteries, tiles, ceramics, glass and others.

One of the purest of the clays, composed chiefly of the mineral kaolinite usually formed when granite is changed by hydrothermal metamorphism. Usage of the terms china clay and kaolin is not well defined; sometimes they are used synonymously for a group of similar clays, and sometimes kaolin refers to those obtained in the United States and china clay to those that are imported. Some authorities term as china clays the more plastic of the kaolins. China clays have long been used in the ceramic industry, especially in fine porcelains, because they can be easily molded, have a fine texture, and are white when fired. France’s clays are made into the famous Sèvres (see A. Brongniart ) and Limoges potteries. These clays are also used as a filler in making paper. In the United States, deposits are found primarily in Georgia, North Carolina, and Pennsylvania; china clay is also mined in England (Cornwall) and France.

The formation of granite
At one time, most of what is now the British Isles was covered by sea, upon the bed of which vast deposits of mud and silt collected.

In time, the accumulated weight of the sediments caused them to become compressed and hardened, converting them from loose sediments into highly cleavable forms of rock – the slates and shales which still abound on the costs of Cornwall and Devon to this day.

At the time when the sediments were being laid down, great landmasses were drifting towards each other on a collision course. The pressures generated by this movement caused the seabed to fracture and fold. The folding process was accompanied by intense subterranean activity, the masses of molten rock forced their way upwards.

When the rock cooled, it became granite, a rock made of a mixture of quartz, feldspar and mica. The formation of the granite took place between 290 and 270 million years ago and today it forms the rocky backbone of the south-west of England, being exposed in the Scilly Isles, Lands End, Carnmenelis, Hensbarrow near St Austell, Bodmin Moor and Dartmoor.

The formation of china clay
Granite is one of the commonest igneous rocks, but varies considerably in its composition from place to place. While the quartz is never anything but quartz, the feldspar can be a silicate of alumina with potash, soda or lime and the mica the potash-rich muscovite or the iron-rich biotite.

In some parts of the South West, the feldspar in the granite is higher in its soda content than its potash content and these places are where china clay is found today. It came into being through a complex sequence of events. While the molten rock was still cooling, it was attacked successively by steam, boron, fluorine and tin vapour, these acting on the alkali content of the feldspar and converting it into china clay.

The South Western granite has been converted into china clay only in those areas where the feldspar contained the necessary high soda content. Though no china clay is to be found in the Scilly Isles, it occurs in some places in the Lands End peninsula, at Tregonning Hill, near Helston, at Carnmenellis, on the St Austell moors around Hensbarrow Beacon, on Bodmin Moor and on parts of Dartmoor. The greatest amount of china clay is found on the St Austell moors.The china clay deposits are roughly funnel-shaped, with the widest part uppermost, and the base of these funnels can be as much as 300 metres deep. In certain locations, the deposits occur in clusters, and here one finds the largest of the china clay workings, including Blackpool, Goonbarrow, Littlejohns and Melbur in the St Austell area, Stannon on Bodmin Moor and Lee Moor on Dartmoor. Some of the deposits cover many hectares at the surface, while the deepest of the clay pits currently being worked is some 130 metres deep. To work any pit beyond this depth would mean that the pit would have to be enlarged laterally, as well as in depth.

China clay occurs in the deposits in the form of china clay rock, a mixture of up to 15 per cent china clay and up to 10 per cent mica, and the remainder being quartz. The clay itself varies considerably from pit to pit. In some deposits, such as those at Blackpool, Littlejohns and Goonbarrow, the clay is ideally suited for the filling and coating of paper, while in other deposits, such as Treviscoe and Wheal Remfry, the clay is best suited for the making of ceramics.

The china clay deposits of Cornwall and Devon are known as primary deposits, because the clay is found at the site where it was formed. Deposits of primary clay are found in Czechoslovakia, France, Germany, Spain, parts of the USA and in the USSR, but in all these the feldspars in the granite have been broken down by weathering, and the deposits of clay are strictly limited to the depth to which the weathering has penetrated: because of this, the clay reserves are much smaller than in Cornwall and Devon.

In Czechoslovakia in particular, where the china clay industry has been in existence for some two centuries, many of the largest deposits have become completely worked out and only the discovery of fresh deposits has enabled the Czech clay industry to continue.

In some countries, including Greece, Hungary, Iceland, Italy, Mexico and Turkey, there are somewhat different deposits of clay, which are also primary in nature. Here, however, the rocks that have undergone alteration were of volcanic origin, and the alternative media have been sulphurous steam and fluids.

Consequently, the clay in these deposits contains minerals, which make it unacceptable for use in either paper or ceramics.

Some china clay deposits are found a long way from the site of their formation, having been formed originally by weathering, and then having been washed away and transported by rivers to the places where they have eventually become deposited. These deposits are known as secondary deposits, and the largest of these in the world are found in the USA, in Georgia, South Carolina and Alabama. The clay occurs in beds up to 20 metres thick and is suitable for use after processing in paper, but not in ceramics, because of its high titanium content. Imerys is a major producer of china clay in Georgia.

Development of the China Clay Industry
The early history of the industry is, as would be expected, very much concerned with the discovery and production of china clays for use in ceramics. The story, though, starts thousands of years ago and thousands of miles away.

China, the pure white porcelain used by the Chinese, was discovered many thousands of years ago and has always been a much-prized material. Despite many attempts to find sources elsewhere, it remained elusive until a few deposits were found in some parts of Europe and in America early in the eighteenth century. The search to find deposits in England was increased.

When china clay, or kaolin, was discovered in England, it was realised that it was of a much finer quality than found elsewhere in Europe. A Quaker apothecary-cum-potter, William Cookworthy made the discovery in Cornwall in 1746. He experimented with various samples and in 1768 he took out a patent to use the material, soon producing items at his Plymouth Porcelain Factory. Until that time English pottery had consisted of coarse earthenware and stoneware ceramics and had suffered considerable competition from elsewhere.

As more potteries made use of porcelain, so the demand grew and by the early nineteenth century the kaolin industry had become highly successful, with many of the Potters owning rights to mine the material for themselves. In addition, by the middle of the nineteenth century, china clay was increasingly being used as a raw material by the developing paper industry.

Early in the twentieth century, the industry was made up of some seventy or so individual producers, each competing on price with little regard for marketing or standards. There was almost no capital investment or product development and over-production was great, wages were low and working conditions were poor.

Despite this, by 1910, production was approaching a million tons a year and paper had completely overtaken ceramics as the prime user of china clay. Over 75% of output was exported, with North America and Europe being major markets. The china clay industry in Cornwall and Devon held a virtual monopoly on the supply of that mineral to the world market. Just after the First World War, the three leading producers joined forces – forming English China Clays Limited in 1919, placing almost 50% of the industry’s capacity under one banner.

China Clay Production
China clay mining is a complicated process which can be split into three distinct sections – opencast mining, refining and drying

Known as pit operations, this process firstly requires the removal of ground overlying the clay. This is known as overburden, which can vary in depth between one and fifteen metres. Once the clay is exposed, the method of mining is best described as a hydraulic mining process. This means, quite simply, that a jet of water under enormous pressure is fired at the pit face from a water cannon known in the industry as a monitor. This liberates from the quarry face the china clay, together with sand and mica.

The material runs in slurry form to the lowest part of the pit, known as the sink, where it is lifted by centrifugal pumps to mechanical sand classifiers, where the more coarse sand elements are removed. The sand is disposed of on belt conveyors, which deposit it on low profile tips that can then be landscaped and seeded with grass.

Having removed the coarsest of the sand, the clay suspension is then transported by underground pipeline to the second process: refining.

Refining
Refining consists of a series of mineral processing techniques – predominantly sedimentation – designed to remove the smaller sized waste particles, mainly minerals such as very fine quartz, mica and feldspar, leaving only the required china clay behind.

Value can also be added to the clay at this stage by a variety of processes designed to engineer size and shape of the product, together with the use of a chemical bleaching process that improves its whiteness

Having refined the clay, it is moved on to the final process: drying.

Drying
Drying consists of firstly converting the liquid clay into a solid material by a process known as filtration. The products of filtration normally have a moisture content of about 25%.

Passing the clay through a thermal drier further reduces this moisture content. The driers are fired by natural gas and see a product emerging at around 10% moisture. The product is normally sold in pelletised form – particle size ranges from 6-12mm.

Despite its extensive china clay deposits in Cornwall and Devon, Imerys continually researches new methods of extending the life of its reserves. For example, new refining techniques have been developed to obtain more china clay per matrix and sophisticated technical innovations provide the ability to adjust particle size. Consequently, the company is confident that its reserves are sufficient to last for many generations.

China Clay Industry Statistics
Clay bearing ground in mid-Cornwall covers approximately 25 square miles.

Nine tonnes of waste rock and debris are produced for every one tonne of china clay.

Imerys operates 17 pits in the UK. 14 of these are situated in Cornwall; 12 concentrated in the St Austell area. The three pits outside of Cornwall are situated on the south-western side of Dartmoor, an area known as Lee Moor.

As well as Imerys, there are two independent producers: Goonvean in Cornwall and Watts Blake Bearne in Devon. Goonvean operates five pits and WBB two pits.

87% of the china clay produced in Cornwall is exported and some 60 grades are produced. The major markets are Western Europe, with the Nordic countries being the most important.

Clay for export is normally despatched through the local port of Par, taking 30% of output, and the deep-water port of Fowey, taking 70%. Clay into the UK market is distributed equally between road and rail.

Imerys employs over 2,500 people directly involved in the mining and distribution of china clay to the ports. The value to the local economy is immense, with over £120 million going directly into the Cornish economy. About half this figure is paid in wages, with the remainder being used to buy goods and services.

Uses of China Clay
Earliest uses
List of uses in “The Hensbarrow Granite District”, the first detailed account of the china clay industry, written by the distinguished Cornish geologist J. F. Collins, F.G.S. in 1878:

The first use to which china clay was applied in the West of England was, as already stated, the manufacture of porcelain and this is still popularly believed to be its sole use. This is, however, by no means the case, probably not more than one-third of the clay now being produced being so used.

Large quantities are used for “bleaching”, i.e filling for the spaces between the threads of calicoes and other cotton goods and also as a material for giving weight to cotton yarn; and still larger quantities are used by papermakers to give “body” to their papers, especially to printing papers.

The manufacture of alum, sulphate of alumina and ultramarine uses up large quantities annually, besides which small quantities are used by manufacturing and colour makers, photographers and others. It has also been used, not avowedly however, as a “body” in the composition of some artificial manures, the utilisation of sewage and even in the adulteration of flour.

Should the present low prices be maintained its use will no doubt be still more largely extended in directions as yet unsuspected.

Early 20th Century
J. Allen Howe’s “Handbook of kaolin, china clay and china stone” was published in 1914 and listed the following uses:

China clay in ceramic manufacture, porcelain; bone china; earthenware; white tile body; graniteware; white stoneware; glazes.

Paper manufacturing (note: some 60% of output was being used by the paper industry by the early 20th Century)

Miscellaneous, paint; plaster; alum; ultramarine; whitewash; drugs; soap and face powder; wine clarification; polishing powders; lead pencils.

Mid 20th century
List of uses published in the “Technical Salesman’s Handbook” issued by E.C.L.P. & Co. Ltd in 1954:

Paper and board, coating clays; fillers; brush coating clays; machine coating clays.

Ceramics (excluding refractories), bone china; hard porcelain (including tiles, tableware, sanitary and electrical porcelain); fine earthenware; earthenware (lower grade); earthenware (sanitary); porous wall tiles; electrical porcelain (England); semi-vitreous china (American); semi-vitreous porcelain (American); hotel china (American); household china (American); belleek (American); glazes (mill additions and frit additions); porcelain enamels; radiants.
Rubber
Paint and distemper
Leather
Cosmetics, insecticides, dusting and medicinal
Textiles
Linoleum
White cement
Ultramarine
Plastics

Miscellaneous, soap; cleaners; inks; fuses; pencils; grinding wheels; welding rods; boiler coverings; asbestos; dyes; accumulator cases; lubricants (extrusion).

Today
Paper, Kaolin performs two quite separate functions in papermaking. As a filler or loading, it is incorporated within the body of the paper, both reducing its overall cost and improving its printing properties. It is also a coating pigment, enhancing the surface properties of the paper, such as brightness, smoothness and gloss, thus allowing the accurate reproduction of colour printing.

Type of paper
Board Printing and writing paper
Newsprint Typical kaolin content (%)
up to 10
up to 30
up to 8

Ceramics, Kaolin was originally used in the manufacture of whiteware ceramics. The amount of kaolin used for this purpose is now greatly exceeded by that used in the paper industry. The ceramic and refractories industries remain a major market, accounting for nearly one million tonnes of kaolin in Western Europe.

The major markets for English kaolins in the whiteware ceramic industry are tableware, vitreous-china sanitaryware, wall tiles (in the UK), electrical porcelain and glazes. In addition, kaolin and calcined clay are used for refractory applications.

Paint applications: Water based decorative paints: gloss; semi-gloss and silk; exterior matt – smooth and textured; interior matt; primers.

Solvent based decorative paints: gloss; semi-gloss and eggshell; matt; undercoats; primers. Protective and OEM coatings: metal primers; furniture lacquers; domestic appliance finishes; electrophoresis coatings; coil coatings; traffic markings; printing inks.

Rubber applications: Kaolin is incorporated into both natural and synthetic rubber compounds and is the rubber industry’s most widely used non-black filler with reinforcing properties:

Cable insulations: cable sheath; hose; extrusions; belting; footware; pharmaceutical; seals; general mouldings; plant lining; domestic mouldings; latex; tyres/inner tubes.

Plastics applications: Kaolin has many uses as a filler in plastics:

Speciality films: PE master batch; PE cables; PE film; pPVC cables; pPVC extrusions; pPVC plastisols; PP mouldings; polyamide mouldings; PBT/PET mouldings; unsaturated polyester; urea formaldehyde; phenol formaldehyde.

Metakaolin for the building and construction industry. A high quality pozzolanic material which is blended with Portland cement in order to improve the durability of concrete and mortars.

White cement: In the production of white cement, iron is a deleterious component which can be avoided by using kaolin, an alumino silicate with a very low iron content.

Glass fibre: The preferred raw material for introducing alumina to glass compositions for glass fibre manufacture is kaolin.

Agricultural industries: The caking or setting of granular fertilisers (prills), is a serious problem since the caked mass must be broken down into its individual particles before it can once again become a free-flowing product. Kaolin, some of which is amine-coated, acts a non-stick coating to the fertiliser prill. As colour is of no significance, cheaper grades can be used.

Other industries: Pharmaceutical applications; quality leather; textiles; inks, dyes, adhesives, crayons and pencils; toothpastes and cosmetic applications; chemicals industry.

Into the future
Some of the uses listed below are already commonplace while others are innovative and in the development stage.

Plastic film, Video and audio tapes, where clays are used as anti-blocking agents.

Laundry products, Washing powders and detergents.

Decorative concrete, Mortars and renders.

Mark-resistant polypropylene for automotive use Thermoset mouldings for baths, shower trays, etc.

Lightweight concrete Water treatment systems

Biotechnology, Ability of lightweight high-strength ceramic materials to support micro-organisms

China Clay Or Kaolin In Paint

When we use the terms china clay or kaolin, we refer only to the white earthy pigments of silica and alumina, that are used in paints and colors. We pass by the species of earth known as pipe clay, potters’ clay or fire clay, for which there is no use in paint making, because of their color and other special characteristics. While the general term for white clay is kaolin, this name is used among our trade for the white clay mined in various parts of the United States, principally in Alabama and South Carolina, but also in some Northern localities. This will answer many purposes in the line of paint manufacture, but where a really soft and very white material of this character is required the imported article known as china clay, which is mined and prepared for export at Cornwall, England, is preferred. Pigments equaling this English china clay are also found in other countries, notably in Germany and France, but for commercial reasons hardly ever imported into this market. G. H. Hurst, in his work on “Painters’ Colors, Oils and Varnishes,” describes the origin, and also the manufacture of china clay, as it is being carried on at the clay works at Cornwall, so that it will be unnecessary to devote space to the subject here. All the white clays for use in paint must consist of silica and alumina with some combined water, otherwise they will not fulfill their function. The texture varies somewhat according to this composition, some being more unctuous than others. If silica were not present in the pigment it would have no tooth whatever and with oil produce a liverlike mixture. The china clay that by chemical analysis approaches closest to the following composition may be considered best for general use in paint; 47 per cent silica, Si02; 39 per cent alumina, AL203; 13 per cent water, H20 (allowing 1 per cent for free moisture, magnesia, potash and iron). The color maker will, however, prefer the pigment that is entirely free of iron oxide. Domestic kaolin will vary somewhat from this analysis, generally consisting of more silica and showing appreciable fractions of one per cent of iron oxide and lime. Still fairly large quantities are being used of the domestic article in many special paints, where light weight per gallon is desirable. When china clay is imported it comes in large casks, two to the long ton, and the clay is in lump form, usually containing anywhere from 6 to 10 per cent moisture that has to be driven off before it can be bolted for the use of the paint maker, hence the price of bolted China clay is so much in advance over the quotation of the importer. Enormous quantities of this clay are imported for industrial purposes, where it is used in the pulped form and in that case the amount of moisture cuts a figure only as to its weight. The clay absorbs some moisture in transit and on being stored in the open on wharves, hence the large percentage of water usually found.